Diminishing vortex intensity and improving heat transfer by applying magnetic field on an injectable slip microchannel containing FMWNT/water nanofluid

In this study, heat transfer and entropy generation were investigated in a microchannel containing FMWNT/water nanofluids given the slip condition. The main focus was on utilizing injection technique in the presence of the magnetic field. The injection from the upper high-temperature wall was incorporated into the flow field. Injection at high Reynolds number causes vortex formation, which ultimately reduces local heat transfer in the adjacent injection zone. By applying the magnetic field, the vortex intensity as well as boundary layer thickness was diminished which in turn improved the heat transfer. Based on numerical results, at higher nanoparticle volume fraction, the effect of the magnetic field on heat transfer enhancement was amplified. Moreover, at higher Reynolds numbers, the magnetic field efficacy is more obvious. The highest heat transfer occurred at the highest values of the Hartmann and Reynolds numbers and eventually the nanoparticle volume fraction. Owing to applying the magnetic field on the injectable microchannel containing nanofluid, heat transfer improvement can reach up to 79%. From the second law prospective, the entropy generation intensified by 82.8%.

     

Limit cycle bifurcation by perturbing a cuspidal loop of order 2 in a Hamiltonian system

This paper deals with the analytical property of the first Melnikov function for general Hamiltonian systems possessing a cuspidal loop of order 2 and its expansion at the Hamiltonian value corresponding to the loop. The explicit formulas for the first coefficients of the expansion have been given. We prove that at least 13 limit cycles can bifurcate from the cuspidal loop of order 2 under certain conditions. Then we consider the cyclicity of a cuspidal loop in some Liénard and Hamiltonian systems, and determine the number of limit cycles that can bifurcate from the perturbed system.     

Computational Modeling of Liquid Droplets Moving on Rough Surfaces

We present a de-coupled approach for computational modeling of liquid droplets moving on rough substrate surfaces. The computational model comprises solving the membrane deformation problem and the fluid flow problem in a segregated manner. The droplet shape is first computed by solving the Young-Laplace equation where contact constraints, due to the droplet-substrate contact, are applied through the penalty method [1]. The resulting configuration constitutes the domain for the fluid flow problem, where the bulk fluid behavior is modeled by the unsteady Stokes' flow model expressed in Arbitrary Lagrangian-Eulerian (ALE) framework. The entire analysis is performed in the framework of Finite Element Method (FEM). Application of the approach to the case of a droplet moving on a rough surface is presented as an example. (© 2013 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim)     

Flavonoid Constituents from Spiraea brahuica

Sparins A–C ( 1 – 3 , resp.), three new flavonoids, were isolated from the CHCl₃ subfraction of the EtOH extract of the whole plant of Spiraea brahuica, along with 3′,7‐di‐O‐methylquercetin ( 4 ) and luteolin 7‐β‐D ‐glucopyranoside ( 5 ), reported for the first time from this species. The structures of the new compounds were elucidated by spectroscopic techniques including MS and 2D‐NMR spectroscopy.     

Two new triterpenoids from Zygophyllum eurypterum

Two new triterpenoids trivially named as atriplicoide A and B were isolated from the n-BuOH extract of the whole plant of Zygophyllum eurypterum. Based on EI-MS, IR, 1H- and 13C-NMR, and 2D-NMR (HMQC, HMBC, COSY and NOESY) data, the structures of the new compounds were determined as 30-carboxy-3beta,24-dihydroxy-urs-28,13beta-lactam-N-acetate (1) and 3beta,24-dihydroxyursan-28,13beta-olide (2).     

Insights into the inhibitory potential of selective phytochemicals against Mpro of 2019-nCoV: a computer-aided study

Structural Chemistry - At the end of December 2019, a novel strain of coronavirus, given the name of 2019-nCoV, emerged for exhibiting symptoms of severe acute respiratory syndrome. The virus is...     

Numerical study of nonlinear mixed convection inside stagnation-point flow over surface-reactive cylinder embedded in porous media

Nonlinear mixed convection of heat and mass in a stagnation-point flow of an impinging jet over a solid cylinder embedded in a porous medium is investigated by applying a similarity technique. The problem involves a heterogenous chemical reaction on the surface of the cylinder and nonlinear heat generation in the porous solid. The conducted analysis considers combined heat and mass transfer through inclusions of Soret and Dufour effects and predicts the velocity, temperature and concentration fields as well as the average Nusselt and Sherwood number. It is found that intensification of the nonlinear convection results in development of higher axial velocities over the cylinder and reduces the thickness of thermal and concentration boundary layers. Hence, consideration of nonlinear convection can lead to prediction of higher Nusselt and Sherwood numbers. Further, the investigation reveals that the porous system deviates from local thermal equilibrium at higher Reynolds numbers and mixed convection parameter.

     

Experimental study on rheological behavior of water–ethylene glycol mixture in the presence of functionalized multi-walled carbon nanotubes

Journal of Thermal Analysis and Calorimetry - This paper examines the rheological behavior of water (60%vol.)–ethylene glycol (40%vol.) mixture in the presence of functionalized multi-walled...     

Tin sulfide nanoparticles supported on activated carbon as an efficient and reusable Lewis acid catalyst for three-component one-pot synthesis of 4H-pyrano[2,3-c]pyrazole derivatives

Tin sulfide nanoparticles (SnS‐NPs) were prepared in aqueous solution at room temperature on the surface of activated carbon (AC) and were investigated using field‐emission scanning electron mi‐croscop...